dichotomy of assumptions

Published 2024-03-03T01:45:00.003Z by Physics Derivation Graph

In Physics there are some assumptions that form a dichotomy:

In the dichotomy of assumptions, one of the two assumptions is reflective of reality, and the other is an oversimplification. The oversimplification is related to reality by assumptions, constraints, and limits. 

(I define "oversimplification" as the extension of useful assumptions to incorrect regions.)

Another case where oversimplification is the link between domains is quantum physics and (classical) statistical physics. Quantum particles are either Fermions (odd half integer spin) or Bosons (integer spin), but that is practically irrelevant for large ensembles of particles at room temperature. The aspects that get measured at one scale (e.g., particle velocity) are related to but separate from metrics at another scale (e.g, temperature, entropy). Mathematically this transition manifests as the switch from summation to integration.


So what? 
This is a new-to-me category of derivations which span domains. What constitutes a domain is set by the assumptions that form the boundaries, and oversimplification is how to cross the boundaries. 

What boundaries should the Physics Derivation Graph transgress? What oversimplifications are adjacent?

The evidences of dissonance (e.g, Mercury’s perihelion based on Newtonian gravitation versus relativity, the Deflection of Starlight; source) are not relevant for bridging domains. They are illustrations of the oversimplification.


Update 2024-03-10: on the page https://en.wikipedia.org/wiki/Phase_space#Quantum_mechanics

"by expressing quantum mechanics in phase space (the same ambit as for classical mechanics), the Weyl map facilitates recognition of quantum mechanics as a deformation (generalization) of classical mechanics, with deformation parameter ħ/S, where S is the action of the relevant process. (Other familiar deformations in physics involve the deformation of classical Newtonian into relativistic mechanics, with deformation parameter v/c; or the deformation of Newtonian gravity into general relativity, with deformation parameter Schwarzschild radius/characteristic dimension.)
 
Classical expressions, observables, and operations (such as Poisson brackets) are modified by ħ-dependent quantum corrections, as the conventional commutative multiplication applying in classical mechanics is generalized to the noncommutative star-multiplication characterizing quantum mechanics and underlying its uncertainty principle."
See also https://en.wikipedia.org/wiki/Wigner%E2%80%93Weyl_transform#Deformation_quantization
prompt

In Physics there are dichotomies of assumptions like

One of the two assumptions is reflective of reality and the other is an oversimplification. The oversimplification is related to reality by assumptions, constraints, and limits.

What are other examples of these dichotomies in Physics?

Using https://aistudio.google.com/prompts
2025-01-20: Gemini 2.0 Flash Thinking Experimental: thoughts

Here's a thinking process to arrive at the list of physics dichotomies:

  1. Understand the Core Request: The request asks for pairs of opposing assumptions in physics, where one is a simpler, often historically earlier, model and the other is a more nuanced, "real" (or currently accepted as more accurate) version. The key is identifying the simplification and how it's related to the more accurate model.
  2. Brainstorm Broad Areas of Physics: To generate diverse examples, think about the major branches of physics:
    • Classical Mechanics (motion, forces)
    • Electromagnetism (light, fields)
    • Thermodynamics (heat, energy)
    • Quantum Mechanics (atoms, subatomic particles)
    • Relativity (space, time, gravity)
  3. Consider Key Concepts Within Each Area: For each area, brainstorm core concepts and how they are described at different levels of approximation.
    • **Classical Mechanics:** Think about how objects are treated – point masses vs. extended bodies, rigid vs. deformable. Consider forces – are they always instantaneous? What about friction and energy loss?
    • **Electromagnetism:** The prompt itself gives a great example (constant vs. variable speed of light, which links to the wave/particle duality). Think about the nature of electric and magnetic fields – discrete charges or continuous distributions?
    • **Thermodynamics:** What about the nature of matter? Is it perfectly divisible or are there ultimate particles? Is heat a fluid (caloric theory) or the motion of particles?
    • **Quantum Mechanics:** This field is rich with dichotomies. Think about the nature of particles – are they particles or waves? Are their properties definite before measurement? Is information conserved?
    • **Relativity:** The prompt's example of the speed of light falls here. Think about space and time – are they absolute or relative? Is spacetime flat or curved?
  4. Formulate Dichotomies: For each brainstormed concept, try to form a clear "either/or" statement representing the simplification and the more accurate model.
    • *Example (Classical Mechanics):* Point mass vs. Extended Body. The point mass assumption simplifies calculations but doesn't capture rotational motion or internal structure.
    • *Example (Electromagnetism):* Light as a Wave vs. Light as a Particle. The wave model explained diffraction, but the particle model explained the photoelectric effect. Now we have wave-particle duality.
    • *Example (Quantum Mechanics):* Deterministic Trajectories vs. Probabilistic Descriptions. Classical physics assumes we can know both position and momentum perfectly. Quantum mechanics introduces uncertainty.
  5. Refine and Add Details: Once you have a list of dichotomies, add details explaining:
    • Which is the simplification.
    • How the simplification is useful (e.g., for easier calculations).
    • The assumptions, constraints, and limits under which the simplification holds.
    • How the more accurate model relates to the simplification.
  6. Organize and Categorize: Group similar dichotomies together for better readability and flow. Using the broad areas of physics as categories works well.
  7. Review and Expand: Read through the list. Are there any obvious omissions? Can any of the explanations be clearer? Consider adding a brief introductory and concluding paragraph to frame the discussion. For example, explicitly mentioning the historical progression of these ideas can be valuable.

**Self-Correction Example during the process:**

Initial thought: "Classical vs. Quantum" as a dichotomy.
Correction: While a valid broad distinction, it's too general for the specific prompt. The prompt asks for *specific assumptions*. Refine this to find more concrete examples *within* the transition from classical to quantum, like the deterministic vs. probabilistic nature of particle paths.

By following these steps, and iterating through brainstorming and refinement, you can generate a comprehensive and well-explained list of physics dichotomies like the example provided in the initial prompt.

2025-01-20: Gemini 2.0 Flash Thinking Experimental: response

You've hit upon a fascinating aspect of how physics progresses! Many of our foundational concepts started as convenient simplifications that, upon closer examination and with more advanced tools, revealed themselves to be more nuanced. Here are some other examples of such dichotomies in physics:

**Mechanics & Motion:**

**Electromagnetism:**

**Thermodynamics & Statistical Mechanics:**

**Quantum Mechanics:**

**Relativity:**

These are just a few examples, and the lines between the "simplification" and "reality" can sometimes be blurry and depend on the specific context and the level of precision required. Physics progresses by refining these simplifications, understanding their limitations, and developing more accurate models that incorporate the complexities of reality. This process often involves the introduction of new concepts, mathematical tools, and experimental techniques.

prompt

Are there examples of Derivations of Mathematical Physics which span these assumptions?

2025-01-20: Gemini 2.0 Flash Thinking Experimental: thoughts Here's a breakdown of the thinking process to generate examples of derivations spanning those dichotomies:
  1. **Understand the Core Request:** The user wants examples of *mathematical derivations* in physics where we start with a simplified assumption and then refine it to incorporate the more "realistic" scenario. This means the derivation should show how the simplified case relates to the more complex one.
  2. **Review Previous Examples:** Look back at the dichotomies listed previously. These are the starting points for the derivations.
  3. **Choose Dichotomies Suitable for Derivations:** Not all dichotomies lend themselves equally well to explicit mathematical derivations. Focus on those where a clear mathematical bridge exists between the simplified and complex cases. For example, "isolated vs. open system" is a concept, but deriving the thermodynamics of an open system *from* an isolated one is less direct than, say, going from a point particle to a rigid body.
  4. **Select Specific Examples within Chosen Dichotomies:** For each suitable dichotomy, think of a concrete physical scenario that exemplifies it and allows for a mathematical treatment.
  5. **Outline the "Simplified" Derivation:** Describe the mathematical steps involved in the simplified case. This should be a standard result in introductory physics. Focus on the key assumptions being made.
  6. **Outline the "More Realistic" Derivation:** Describe how the derivation changes when the simplifying assumption is relaxed. Highlight the new terms or concepts that need to be introduced. Crucially, *show how the simplified result is recovered as a limit or special case of the more realistic one.* This is the core of the "spanning" aspect.
  7. **Emphasize the Bridging Elements:** Point out the mathematical connections between the two derivations. This could involve:
    • Taking a limit (e.g., size approaching zero).
    • Setting a parameter to zero (e.g., resistance).
    • Integrating over a continuous distribution to represent the discrete case.
    • Introducing additional terms or degrees of freedom.
  8. **Provide Concrete Examples:** Use specific equations and mathematical expressions to illustrate the derivations. This makes the explanation much clearer.
  9. **Consider Different Areas of Physics:** Aim for examples across mechanics, electromagnetism, and potentially other areas to show the broad applicability of this concept.
  10. **Structure for Clarity:** Organize the examples logically, clearly labeling the simplified and more realistic derivations and the bridging elements. Use bullet points and clear language.

**Self-Correction/Refinement During the Process:**

**Initial thought:** "Can I derive the Navier-Stokes equations from the ideal gas law?" **Correction:** While related, it's not a direct derivation spanning the "discrete vs. continuous" dichotomy in the same way as the charge example. Focus on clearer, more direct mathematical links.

**Initial thought:** "Should I include quantum mechanics?" **Correction:** While superposition is a good example of the dichotomy, showing a direct mathematical *derivation* from the "definite property" case is more subtle and might require advanced quantum field theory. Stick to more elementary examples for clarity.

**Focus on the "derivation" aspect:** Make sure the examples genuinely show a mathematical path from the simplified to the complex, not just a conceptual comparison.

By following these steps and refining the examples, the goal is to produce a clear and illustrative answer that directly addresses the user's question.

2025-01-20: Gemini 2.0 Flash Thinking Experimental: response

Yes, absolutely! There are many examples where derivations in mathematical physics start with a simplified assumption and are then extended to incorporate the more realistic scenario, showing how the simplification arises as a special case. Here are some examples tied to the dichotomies we discussed:

Point Particle to Extended Body (Mechanics):

Discrete Charges to Continuous Charge Distribution (Electromagnetism):

Ideal Conductor to Real Conductor (Electromagnetism):

Reversible Process to Irreversible Process (Thermodynamics):

Flat Spacetime to Curved Spacetime (Relativity):

How These Derivations Span the Assumptions:

In each of these examples, the more "realistic" derivation:

These derivations are not just about having two separate formulas; they are about understanding the relationship between the simplified model and the more accurate one. The mathematical steps often explicitly show how the simplifying assumptions restrict the more general case. This is a core part of how physics builds upon previous understanding and refines its models of reality.

prompt Provide an example of a derivation that bridges the assumptions of classical mechanics and quantum mechanics.
2025-01-20: Gemini 2.0 Flash Thinking Experimental: thoughts

Here's a breakdown of the thinking process behind constructing the example of the quantum harmonic oscillator derivation bridging classical and quantum mechanics:

  1. **Identify the Core Dichotomy:** The request asks for a bridge between classical and quantum mechanics. The fundamental difference lies in how these theories describe the behavior of particles – deterministic trajectories vs. probabilistic wave functions.
  2. **Choose a Concrete Example:** A good example needs to be simple enough to illustrate the connection without getting bogged down in advanced mathematics, yet fundamental enough to be meaningful in both frameworks. The **harmonic oscillator** is a perfect choice because:
    • It's solvable analytically in both classical and quantum mechanics.
    • It's a ubiquitous model for many physical systems (vibrations, oscillations in fields, etc.).
    • The classical solution provides a clear picture of deterministic motion.
  3. **Outline the Classical Derivation:**
    • **Start with Newton's Second Law:** This is the foundation of classical mechanics.
    • **Apply to the Harmonic Oscillator:** Introduce the restoring force proportional to displacement (`F = -kx`).
    • **Solve the Differential Equation:** This yields the sinusoidal solution for position as a function of time, demonstrating the deterministic nature of the motion (knowing initial conditions fully determines the future).
    • **Identify Key Classical Quantities:** Focus on energy, which is a continuous quantity in the classical picture. Express the total energy in terms of position and velocity (or amplitude and angular frequency).
  4. **Outline the Quantum Derivation:**
    • **Start with the Schrödinger Equation:** This is the fundamental equation of quantum mechanics.
    • **Apply to the Harmonic Oscillator:** Introduce the potential energy function (`V(x) = 1/2 kx^2`).
    • **Solve the Schrödinger Equation:** This involves finding the stationary states (energy eigenstates) and their corresponding wave functions. This is where the mathematical complexity increases.
    • **Key Quantum Concepts:** Emphasize the quantization of energy levels (discrete values), the probabilistic interpretation of the wave function (probability density of finding the particle), and the existence of a zero-point energy.
  5. **Establish the Bridge - The Correspondence Principle:**
    • **State the Principle:** Explain Bohr's Correspondence Principle – quantum mechanics should reproduce classical results in the limit of large quantum numbers or macroscopic systems.
    • **Show the Connection through Energy Levels:** Demonstrate that as the quantum number `n` becomes large, the energy difference between adjacent levels becomes much smaller than the energy itself. This makes the energy spectrum appear nearly continuous, approaching the classical picture.
    • **Show the Connection through Probability Distributions:** Explain that for high quantum numbers, the probability distribution of the particle's position starts to resemble the classical probability of finding the particle at a given location (more likely near the turning points).
    • **Connect to Classical Frequency:** Highlight that the frequency of transitions between adjacent high-energy levels approaches the classical oscillation frequency.
  6. **Discuss the Role of Planck's Constant:** Emphasize that Planck's constant (`ħ`) is the "bridge" mathematically. It's present in the quantum mechanical description and its small value is why quantum effects are not readily apparent in the macroscopic world. Taking the limit `ħ → 0` (formally) recovers classical mechanics.
  7. **Structure the Explanation:** Organize the answer logically with clear headings and bullet points for readability. Start with the classical derivation, move to the quantum derivation, and then explicitly connect them using the correspondence principle.
  8. **Refine and Clarify:** Review the explanation for clarity, accuracy, and completeness. Ensure that the key differences and connections between the classical and quantum descriptions are clearly articulated. Use simple language where possible while maintaining scientific rigor. For example, instead of just saying "solve the Schrödinger equation," briefly mention what kind of solutions are sought (stationary states, energy eigenstates).

Essentially, the process involves: identifying the core difference, selecting a relevant example, outlining the derivations in each framework, and then explicitly demonstrating how the quantum description reduces to the classical one under appropriate limits, highlighting the key concepts and mathematical tools involved.

2025-01-20: Gemini 2.0 Flash Thinking Experimental: response

Bridging Classical and Quantum Mechanics: The Quantum Harmonic Oscillator

A compelling example of a derivation that bridges the assumptions of classical mechanics and quantum mechanics is the treatment of the harmonic oscillator.

Classical Harmonic Oscillator

Assumptions of Classical Mechanics:

Classical Derivation:

Consider a mass m attached to a spring with spring constant k. The restoring force is given by Hooke's Law: F = -kx.

Applying Newton's Second Law (F = ma):

m d2x/dt2 = -kx

This is a second-order linear homogeneous differential equation with the general solution:

x(t) = A cos(ωt + φ)

Where:

The total energy of the classical harmonic oscillator is:

E = 1/2 mv2 + 1/2 kx2 = 1/2 mω2A2 = 1/2 kA2

Importantly, in classical mechanics, the energy E can take any continuous value depending on the amplitude A.

Quantum Harmonic Oscillator

Assumptions of Quantum Mechanics:

Quantum Derivation:

The time-independent Schrödinger equation for a one-dimensional system is:

2/2m d2ψ(x)/dx2 + V(x)ψ(x) = Eψ(x)

For the harmonic oscillator, the potential energy is V(x) = 1/2 kx2.

Solving this differential equation (which involves techniques like using ladder operators or series solutions) yields the allowed energy levels:

En = (n + 1/2)ħω

Where:

This result shows that the energy of the quantum harmonic oscillator is quantized; it can only take on specific discrete values. The lowest energy level, E0 = 1/2 ħω, is known as the zero-point energy, a purely quantum mechanical phenomenon with no classical counterpart.

Bridging the Assumptions: The Correspondence Principle

The bridge between the classical and quantum descriptions lies in the Correspondence Principle, formulated by Niels Bohr. This principle states that the predictions of quantum mechanics should approach the predictions of classical mechanics in the limit of large quantum numbers or macroscopic systems.

How the Harmonic Oscillator Demonstrates the Correspondence Principle:

Mathematical Connection:

While the derivations are fundamentally different (classical uses Newton's laws, quantum uses the Schrödinger equation), the **results converge in the appropriate limits**. The classical frequency emerges from the quantum treatment, and the discrete energy levels become effectively continuous at high energies.

Conclusion

The quantum harmonic oscillator provides a beautiful example of how quantum mechanics builds upon and extends classical mechanics. While classical mechanics treats energy as continuous, quantum mechanics reveals its discrete nature. However, the Correspondence Principle ensures that in the appropriate limits, the quantum description seamlessly transitions to the familiar classical behavior. This highlights the power of physical theories to provide accurate descriptions across different scales and regimes.

prompt Provide an example of a derivation that bridges the assumptions of classical mechanics and electromagnetics. Format your response as HTML rather than markdown.
Note: hyperlinks below added outside the LLM as part of my validation the words are not being hallucinated.
2025-01-20: Gemini 2.0 Flash Thinking Experimental: response

Bridging Classical Mechanics and Electromagnetism: Radiation from an Accelerating Charge

One significant example of a derivation that bridges the assumptions of classical mechanics and electromagnetism is the calculation of electromagnetic radiation emitted by an accelerating charged particle. This derivation beautifully combines concepts from both domains.

Classical Mechanics Perspective

Assumptions:

Input from Mechanics:

We start by considering a single point charge q undergoing acceleration a(t). The exact form of the acceleration depends on the forces acting on the charge, which are governed by classical mechanics (e.g., a charge moving in a circle experiences centripetal acceleration).

Classical Electromagnetism Perspective

Assumptions:

Derivation Steps:

  1. Liénard-Wiechert Potentials: We begin by determining the electromagnetic potentials (scalar potential φ and vector potential A) generated by a moving point charge. These are given by the Liénard-Wiechert potentials, which are retarded potentials accounting for the finite speed of light:

    φ(r, t) = \frac{1}{4πε0} qc}{(rc - r · v)}ret

    A(r, t) = \frac{μ0qc}{4π} v}{(rc - r · v)}ret

    Where:

    • r is the vector from the retarded position of the charge to the observation point.
    • v is the velocity of the charge at the retarded time.
    • The subscript 'ret' indicates that these quantities are evaluated at the retarded time t', such that t - t' = |r - r'(t')|/c.

  2. Calculating Electric and Magnetic Fields: The electric field E and magnetic field B are derived from the potentials using:

    E = -∇φ - ∂A/∂t

    B = ∇ × A

    These calculations are lengthy and involve careful differentiation, especially considering the dependence on the retarded time.

  3. Separating Velocity and Acceleration Fields: The resulting electric and magnetic fields can be separated into two parts: velocity fields (which dominate at short distances and are related to the Coulomb field) and acceleration fields (which dominate at large distances and constitute the radiation). The acceleration fields are proportional to the acceleration of the charge.
  4. Poynting Vector and Power Radiated: The power radiated per unit area is given by the Poynting vector:

    S = &frac{1}{μ0} E × B

    For the radiation fields, the Poynting vector points radially outward, indicating energy flow away from the charge.

  5. Larmor's Formula: Integrating the Poynting vector over a closed surface far from the charge yields the total power radiated. For a non-relativistic accelerating charge (v << c), this leads to Larmor's Formula:

    P = &frac{μ0q2a2}{6πc}

    Where a is the magnitude of the acceleration.

  6. Relativistic Generalization (Liénard's Formula): For relativistic accelerations, the formula becomes more complex (Liénard's generalization):

    P = &frac{μ0q2}{6πc} γ6 ( |a|2 - |v × a/c|2 )

    Where γ is the Lorentz factor.

  7. Bridging the Assumptions

    Conclusion

    The derivation of the radiation emitted by an accelerating charge is a prime example of how classical mechanics and electromagnetism are intertwined. Classical mechanics provides the description of the source (the accelerating charge), while classical electromagnetism describes the resulting fields and radiation. This derivation is fundamental in understanding phenomena like radio wave emission from antennas, synchrotron radiation, and bremsstrahlung (braking radiation).

prompt Provide an example of a derivation that bridges the assumptions of classical mechanics and relativity. 
2025-01-20: Gemini 2.0 Flash Thinking Experimental: response

Bridging Classical Mechanics and Relativity: Relativistic Momentum

A fundamental example of a derivation that bridges the assumptions of classical mechanics and special relativity is the derivation of the expression for relativistic momentum.

Classical Mechanics Perspective (Failure at High Speeds)

Assumptions:

The Problem with Classical Momentum:

Classical mechanics works very well for everyday speeds. However, when dealing with speeds approaching the speed of light, it leads to inconsistencies with experimental observations and the principle of relativity (that the laws of physics are the same for all inertial observers).

One crucial issue arises when considering collisions and the conservation of momentum in different inertial frames. If classical momentum is used with Galilean transformations, momentum is not conserved in all inertial frames at relativistic speeds.

Special Relativity Perspective

Assumptions:

Derivation of Relativistic Momentum:

The derivation of relativistic momentum typically involves considering a thought experiment involving an inelastic collision between two identical objects as observed from two different inertial frames of reference. The key is to uphold the principle of conservation of momentum in all inertial frames, a cornerstone of physics.

  1. Consider Two Inertial Frames: Frame S and Frame S', where S' moves with a constant velocity v along the x-axis relative to S.
  2. The Collision: In Frame S', two identical objects A and B have equal and opposite velocities along the y'-axis before colliding inelastically. After the collision, they stick together and are at rest in S'.
  3. Observations in Frame S: Using the velocity addition formulas from special relativity (derived from Lorentz transformations), we determine the velocities of objects A and B in Frame S before the collision. These velocities will have both x and y components.
  4. Classical Momentum Conservation (Fails): If we apply classical momentum conservation in Frame S, we find that momentum is NOT conserved along the y-axis. This indicates that the classical definition of momentum is inadequate at relativistic speeds.
  5. Seeking a Modified Momentum: To preserve the law of conservation of momentum in all inertial frames, we need to modify the definition of momentum. We hypothesize a velocity-dependent factor, γ(u), multiplying the classical momentum, where u is the speed of the object in the given frame. So, the relativistic momentum is proposed to be p = m γ(u) u.
  6. Applying Relativistic Velocity Addition: Using the relativistic velocity addition formulas to transform velocities between the frames and enforcing momentum conservation in both frames allows us to solve for the form of γ(u).
  7. The Lorentz Factor: Through this process, it is found that the velocity-dependent factor must be the Lorentz factor:

    γ(u) = \frac{1}{√(1 - u2/c2)}

  8. Relativistic Momentum Formula: Therefore, the expression for relativistic momentum is:

    p = γ(u) m u = \frac{mu}{√(1 - u2/c2)}

Bridging the Assumptions

Conclusion

The derivation of relativistic momentum is a prime example of how special relativity builds upon and refines classical mechanics. It demonstrates that classical mechanics is a limiting case of relativistic mechanics at low speeds. By upholding fundamental principles like the conservation of momentum and incorporating the postulates of special relativity, we arrive at a more accurate description of motion at all speeds.

prompt Provide an example of a derivation that bridges the assumptions of quantum mechanics and electromagnetics. Format your response as HTML rather than markdown.
2025-01-20: Gemini 2.0 Flash Thinking Experimental: response

Bridging Quantum Mechanics and Electromagnetism: Spontaneous Emission

A cornerstone example of a derivation that bridges the assumptions of quantum mechanics and electromagnetism is the calculation of the rate of spontaneous emission of a photon by an excited atom.

Quantum Mechanics Perspective (Atom)

Assumptions:

Quantum Mechanical Description of the Atom:

Consider an atom with an electron in an excited state |e⟩ with energy Ee. There is a lower energy state |g⟩ (ground state) with energy Eg. In the absence of external fields, the atom can spontaneously transition from the excited state to the ground state.

Classical Electromagnetism Perspective (Radiation Field - Initially Simplified)

Initial Simplified Assumption:

Initially, when first approaching this problem, one might consider a simplified classical picture of the electromagnetic field, perhaps just thinking about the energy difference being released as a classical wave. However, a purely classical treatment fails to explain the discrete nature of photon emission and the concept of spontaneous emission.

Quantum Electrodynamics (QED) Perspective - The Bridge

Assumptions of Quantum Electrodynamics:

Derivation Steps:

  1. Quantization of the Electromagnetic Field: The classical electromagnetic field is treated as a collection of quantum harmonic oscillators, one for each mode (frequency and polarization) of the field. The energy of each mode is quantized in units of ħω. Even the vacuum state has a non-zero energy (zero-point energy).
  2. Interaction Hamiltonian:** The interaction between the atom's electrons and the quantized electromagnetic field is described by an interaction Hamiltonian, which is proportional to the dot product of the atom's dipole moment operator (d) and the electric field operator (E).

    Hint = - d · E

  3. Time-Dependent Perturbation Theory: Since the interaction is relatively weak, we use time-dependent perturbation theory to calculate the transition rate from the initial state (excited atom, no photons in the relevant mode) to the final state (ground state atom, one photon emitted into a specific mode).
  4. Fermi's Golden Rule: Fermi's Golden Rule provides the transition rate (probability per unit time) for transitions between quantum states due to a perturbation:

    Γeg = \frac{2π}{ħ} |⟨f|Hint|i⟩|2 ρ(Ef)

    Where:

    • |i⟩ is the initial state (excited atom, vacuum field).
    • |f⟩ is the final state (ground state atom, one photon).
    • ρ(Ef) is the density of final states (number of photon modes per unit energy around the emitted photon's energy).
  5. Calculating the Matrix Element: The matrix element ⟨f|Hint|i⟩ involves the expectation value of the interaction Hamiltonian between the initial and final states. This involves the dipole moment operator of the atom and the creation and annihilation operators for photons in the electromagnetic field.
  6. Summing over Photon Modes: Since the photon can be emitted in any direction and polarization, we need to sum (or integrate) over all possible modes of the emitted photon. This is where the density of states ρ(Ef) comes in.
  7. Spontaneous Emission Rate: The final result for the spontaneous emission rate (Einstein A coefficient) is:

    A21 = \frac{ω3 |deg|2}{3π ε0 ħ c3}

    Where:

    • ω = (Ee - Eg)/ħ is the angular frequency of the emitted photon.
    • deg = ⟨g|d|e⟩ is the transition dipole moment.

Bridging the Assumptions

Conclusion

The derivation of the spontaneous emission rate is a triumph of quantum electrodynamics, demonstrating how the quantization of both matter and the electromagnetic field leads to phenomena that cannot be explained by classical physics alone. It beautifully bridges the gap between the quantum mechanical description of atoms and the quantum mechanical description of light, providing a fundamental understanding of how atoms emit light.

So that set of LLM ideation provides a map that spans topics:
From https://dreampuf.github.io/GraphvizOnline/
graph G {

 subgraph cluster_classical_mechanics {
  label="classical mechanics";
  
  wave_equation [label="wave equation"];
  
  classical_momentum [label="momentum: p = m v"];
  
  simple_harmonic_oscillator [label="simple harmonic oscillator"];
 };
 
 subgraph cluster_quantum_mechanics {
     label="quantum mechanics";
   quantum_harmonic_oscillator [label="quantum harmonic oscillator"];
 };
 
 correspondence_principle [label="Correspondence Principle"];
simple_harmonic_oscillator -- correspondence_principle;
correspondence_principle -- quantum_harmonic_oscillator;

 subgraph cluster_electromagnetics {
     label="electromagnetics";
     
     maxwells_equations [label="Maxwell's equations"];
     
     larmors_formula [label="Larmor's Formula"];
     
 };
 
 derive_maxwell_from_wave [label="Maxwell from wave"];
 wave_equation -- derive_maxwell_from_wave;
 derive_maxwell_from_wave -- maxwells_equations;
 
 subgraph cluster_relativistic_speed {
     label = "relativisitic speed";
     
     relativistic_momentum [label="p = γ m v"];
     
     lienards_formula [label="Liénard's Formula"];
 }
 
radiation_accelerating_charge [label="Radiation from an Accelerating Charge"];
larmors_formula -- radiation_accelerating_charge;
radiation_accelerating_charge -- lienards_formula;

derive_momentum [label="derive momentum"];
relativistic_momentum -- derive_momentum;
derive_momentum -- classical_momentum;

}